Not with the Navy. You will not know what jobs are open until you sit down with the classifier at MEPS.
Also note that having an exceptionally high ASVAB score (95+) may help your chances of getting a spot in a "full" rate". No guarantees, but your recruiter is more likely to try to get you to sign if you have a competitive score, meaning he will do more to find you an open billet for a particular rate.
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